most citedEnd-Tethered Chains Increase the Local Glass Transition Temperature of Matrix Chains by 45 K Next to Solid Substrates Independent of Chain Length

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cond-mat.soft2023★ 16 cited

End-Tethered Chains Increase the Local Glass Transition Temperature of Matrix Chains by 45 K Next to Solid Substrates Independent of Chain Length

James H. Merrill, Ruoyu Li, Connie B. Roth

The local glass transition temperature Tg of pyrene-labeled polystyrene (PS) chains intermixed with end-tethered PS chains grafted to a neutral silica substrate was measured by flu…