4 papers
Competitive Adsorption of Toluene and Water in MFI-type Zeolites
Gavriel Arbiv, Sambhu Radhakrishnan, Alysson F. Morais +6
Competitive adsorption is a major challenge in understanding catalytic activity, selectivity and reaction mechanisms in confined environments such as zeolites. This study investiga…
Rietveld Refinement and NMR Crystallographic Investigations of Multicomponent Crystals Containing Alkali Metal Chlorides and Urea
Cameron S. Vojvodin, Sean T. Holmes, Christine E. A. Kirschhock +8
New mechanochemical preparations of three multicomponent crystals (MCCs) of the form MCl:urea.nH2O (M = Li+, Na+, and Cs+) are reported. Their structures were determined by an NMR…
Amorphous to Crystalline Transformation: How Cluster Aggregation Drives the Multistep Nucleation of ZIF-8
Sambhu Radhakrishnan, Flip de Jong, Estelle Becquevort +11
Nucleation, the pivotal first step of crystallization, governs essential characteristics of crystallization products, including size distribution, morphology, and polymorphism. Whi…
Hydrated Silicate Ionic Liquids: Ionic Liquids for Silicate Material Synthesis
Dries Vandenabeele, Nikolaus Doppelhammer, Sambhu Radhakrishnan +7
The development of Hydrated Silicate Ionic Liquids, which are hypo-hydrated room temperature melts of alkali silicates, has created new opportunities for synthesizing porous silica…