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physics.chem-ph2025

"Gold-Standard" -Machine Learned and Transferable Potential for Linear Alkanes

Chen Qu, Thomas C. Allison, Apurba Nandi +4

The conformational properties of linear alkanes, CH, have been of intense interest for many years. Experiments and corresponding electronic structure calculations were…

physics.chem-ph2025

The quantum nature of ubiquitous vibrational features revealed for ethylene glycol

Apurba Nandi, Riccardo Conte, Priyanka Pandey +4

Vibrational properties of molecules are of widespread interest and importance in chemistry and biochemistry. The reliability of widely employed approximate computational methods is…

physics.chem-ph2024

Extending the atomic decomposition and many-body representation, a chemistry-motivated monomer-centered approach for machine learning potentials

Qi Yu, Ruitao Ma, Chen Qu +6

Most widely used machine learned (ML) potentials for condensed phase applications rely on many-body permutationally invariant polynomial (PIP) or atom-centered neural networks (NN)…

physics.chem-ph2024

Can We Learn the Energy of Sublimation of Ice from Water Clusters?

Joe Bowman, Qi Yu, Chen Qu +2

This short paper reports a study of the electronic dissociation energies, De, of water clusters from direct ab initio (mostly CCSD(T)) calculations and the q-AQUA and MB-pol potent…

physics.chem-ph2024

-Machine Learning to Elevate DFT-based Potentials and a Force Field to the CCSD(T) Level Illustrated for Ethanol

Apurba Nandi, Priyanka Pandey, Paul L. Houston +5

Progress in machine learning has facilitated the development of potentials that offer both the accuracy of first-principles techniques and vast increases in the speed of evaluation…

physics.chem-ph2024

Tell machine learning potentials what they are needed for: Simulation-oriented training exemplified for glycine

Fuchun Ge, Ran Wang, Chen Qu +6

Machine learning potentials (MLPs) are widely applied as an efficient alternative way to represent potential energy surfaces (PES) in many chemical simulations. The MLPs are often…