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quant-ph2017★ 12 cited
Quantum dynamics of the intramolecular vibrational energy redistribution in OCS: From localization to quasi-thermalization
J. B. Pérez, J. C. Arce
We report a fully quantum-dynamical study of the intramolecular vibrational energy redistribution (IVR) in the electronic ground state of carbonyl sulfide (OCS), which is a prototy…
physics.atom-ph2017★ 9 cited
Potential energy surfaces in atomic structure: The role of Coulomb correlation in the ground state of helium
L. D. Salas, J. C. Arce
For the states of two-electron atoms, we introduce an exact and unique factorization of the internal eigenfunction in terms of a marginal amplitude, which depends functionally…