4 papers
Impact of pressure and temperature on the broadband dielectric response of the HKUST-1 metal-organic framework
Arun S. Babal, Lorenzo Donà, Matthew R. Ryder +8
Herein we employed high-resolution spectroscopic techniques in combination with periodic ab initio density functional theory (DFT) calculations to establish the different polarizat…
Dielectric Properties of Metal-Organic Frameworks Probed via Synchrotron Infrared Reflectivity
Matthew R. Ryder, Zhixin Zeng, Yueting Sun +9
We present the frequency-dependant (dynamic) dielectric response of a group of topical polycrystalline zeolitic imidazolate-based metal-organic framework (MOF) materials in the ext…
Tracking Thermal-Induced Amorphization of a Zeolitic Imidazolate Framework via Synchrotron In Situ Far-Infrared Spectroscopy
Matthew R. Ryder, Thomas D. Bennett, Chris S. Kelley +3
We present the first use of in situ far-infrared spectroscopy to analyze the thermal amorphization of a zeolitic imidazolate framework material. We explain the nature of vibrationa…
Large elastic recovery of zinc dicyanoaurate
Chloe S. Coates, Matthew R. Ryder, Joshua A. Hill +2
We report the mechanical properties of the `giant' negative compressibility material zinc(II) dicyanoaurate, as determined using a combination of single-crystal nanoindentation mea…