5 papers
Monte Carlo simulations of the critical properties of the restricted primitive model
Jean-Michel Caillol
Recent Monte Carlo simulations of the critical point of the restricted primitive model for ionic solutions are reported. Only the continuum version of the model is considered. A fi…
The Diffusion Equation on a Hypersphere
J. -M. Caillol
We study the diffusion equation on the surface of a 4D sphere and obtain a Kubo formula for the diffusion coefficient.
Comparison of simulation methods for charged systems of slab geometry
M. Mazars, J-M. Caillol, J. -J. Weis +1
Using the specific model of a system of like charged ions confined between two planar like charged surfaces, we compare the predictions for the energy and density profile of four s…
Sine-Gordon theory for the equation of state of classical hard-core Coulomb systems. II. High-temperature expansion
J. -L. Raimbault, J. -M. Caillol
We perform a high-temperature expansion of the grand potential of the restrictive primitive model of electrolytes in the frame of the extended sine-Gordon theory exposed in the com…
Sine-Gordon theory for the equation of state of classical hard-core Coulomb systems. I Low fugacity expansion
J. -M. Caillol, J. -L. Raimbault
We present an exact field theoretical representation of the statistical mechanics of classical hard-core Coulomb systems. This approach generalizes the usual sine-Gordon theory val…