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The failure of the master equation for the reactive systems
Maria K. Koleva
Two crucial for the breakdown of the master equation arguments are put forward. The first one is related to the violence of a fundamental requirement to the notion of state (thermo…
"Chaotic" kinetics, macroscopic fluctuations and long-term stability of the catalytic systems
Maria K. Koleva, L. A. Petrov
Our recent interest is focused on establishing the necessary and sufficient conditions that guarantee a long-term stable evolution of both natural and artificial systems. Two neces…
Common and different features between the behavior of the chaotic dynamical systems and the 1/f^alpha(f) noise
Maria K. Koleva, Valery C. Covachev
The major goal of the present paper is to find out the manifestation of the boundedness of fluctuations. Two different subjects are considered: (i) an ergodic Markovian process ass…
Bifurcations Caused by the Diffusion-Induced Noise
Maria K. Koleva, L. A. Petrov
The properties of the fluctuations large enough to induce bifurcations at open chemical systems at steady constraints are studied. The fluctuations that come from the diffusion-ind…
Coarse-Grained Structure of a Physical (Strange) Attractor. Analytical Solution
Maria K. Koleva
The structure of the physical and strange attractors is inherently associated with the boundedness of fluctuations. The idea behind the boundedness is that a stable long-term evolu…
Modelling of Desorption from Small Metal Clusters
Maria K. Koleva, L. A. Petrov
It is found out that there are physical effects, typical of small metal clusters deposited on a non-adsorbing support, that cause a difference between the adsorption properties of…