activity
20142026
most citedH-atom addition and abstraction reactions in mixed CO, H2CO and CH3OH ices: an extended view on complex organic molecule formation

225 citations · 1.5k across the 39 of their papers we have counts for

collaborators

39 papers

astro-ph.IM2026

Quantifying the temperature-dependent yields of N and NH formation in vacuum-ultraviolet-irradiated NH ice

P. Samarth, G. Fedoseev, S. Ioppolo +3

Gas--grain astrochemical models predict that a substantial fraction of elemental nitrogen in dense cores and protoplanetary disks is locked in molecular nitrogen (N), in the ga…

astro-ph.IM2026★ 1 cited

Pulsed ion deflection to overcome detector saturation in cryogenic ice sampling

P. Samarth, M. Bulak, D. Paardekooper +2

In 2014, we introduced a new experimental approach to study the UV photo-processing of cryogenic ices of astrophysical interest using laser ablation in combination with ionization…

astro-ph.GA2026★ 2 cited

In situ characterization of volatile and refractory hydrocarbons produced by UV photolysis of interstellar CH ice

P. Samarth, G. Fedoseev, M. Bulak +5

Acetylene (CH) is commonly observed in star-forming regions, young stellar objects, and the Solar System. Laboratory and theoretical studies have linked this simplest alkyn…

astro-ph.EP2025

Production of linear alkanes via the solid-state hydrogenation of interstellar polyynes

G. Fedoseev, X. Li, G. A. Baratta +2

Highly unsaturated carbon chains, including polyynes, have been detected in many astronomical regions and planetary systems. With the success of the QUIJOTE survey of the TMC-1, th…

astro-ph.GA2024★ 40 cited

Ammonium hydrosulfide (NH4SH) as a potentially significant sulfur sink in interstellar ices

Katerina Slavicinska, Adwin Boogert, Łukasz Tychoniec +6

Sulfur is depleted with respect to its cosmic standard abundance in dense star-forming regions. It has been suggested that this depletion is caused by the freeze-out of sulfur on i…

astro-ph.GA2024★ 10 cited

Formation of carbonyl sulfide (OCS) via SH radicals in interstellar CO-rich ice under dense cloud conditions

Julia C. Santos, Harold Linnartz, Ko-Ju Chuang

Carbonyl sulfide (OCS) is widely observed in the gas phase towards star-forming regions and was the first of the only two sulfur-bearing species detected in interstellar ices so fa…

astro-ph.GA2024★ 23 cited

Formation of S-bearing complex organic molecules in interstellar clouds via ice reactions with C2H2, HS, and atomic H

Julia C. Santos, Joan Enrique-Romero, Thanja Lamberts +2

The chemical network governing interstellar sulfur has been the topic of unrelenting discussion for the past decades due to the conspicuous discrepancy between its expected and obs…

astro-ph.GA2024

Formation of N-bearing complex organic molecules in molecular clouds: Ketenimine, acetonitrile, acetaldimine, and vinylamine via the UV photolysis of CH ice

K. -J. Chuang, C. Jäger, J. C. Santos +1

The solid-state CH chemistry in interstellar HO-rich ice has been proposed to explain astronomically observed complex organic molecules (COMs), including ketene (CH…

astro-ph.GA2024★ 15 cited

A deep search for large complex organic species toward IRAS16293-2422 B at 3 mm with ALMA

P. Nazari, J. S. Y. Cheung, J. Ferrer Asensio +14

Complex organic molecules (COMs) have been detected ubiquitously in protostellar systems. However, at shorter wavelengths (~0.8mm) it is more difficult to detect larger molecules t…

astro-ph.EP2023★ 1 cited

Spatially resolving the volatile sulfur abundance in the HD 100546 protoplanetary disk

Luke Keyte, Mihkel Kama, Ko-Ju Chuang +5

Volatile elements play a crucial role in the formation of planetary systems. Their abundance and distribution in protoplanetary disks provide vital insights into the connection bet…

astro-ph.SR2023★ 6 cited

Interstellar carbonaceous dust erosion induced by X-ray irradiation of water ice in star-forming regions

K. -J. Chuang, C. Jaeger, N. -E. Sie +5

The chemical inventory of protoplanetary midplanes is the basis for forming planetesimals. Among them, solid-state reactions based on CO/CO toward molecular complexity on inter…

astro-ph.GA2023★ 43 cited

CoCCoA: Complex Chemistry in hot Cores with ALMA. Selected oxygen-bearing species

Y. Chen, M. L. van Gelder, P. Nazari +22

Complex organic molecules (COMs) have been observed to be abundant in the gas phase toward protostars. Deep line surveys have been carried out only for a limited number of well-kno…

astro-ph.GA2023★ 26 cited

The hunt for formamide in interstellar ices: A toolkit of laboratory infrared spectra in astronomically relevant ice mixtures and comparisons to ISO, Spitzer, and JWST observations

Katerina Slavicinska, Marina Gomes Rachid, Will Robson Monteiro Rocha +3

This work aims at characterizing the mid-IR spectra of formamide in its pure form as well as in mixtures of the most abundant interstellar ices via laboratory simulation of such ic…

astro-ph.GA2023★ 11 cited

Resonant infrared irradiation of CO and CH3OH interstellar ices

J. C. Santos, K. -J. Chuang, J. G. M. Schrauwen +6

Solid-phase photo-processes involving icy dust grains greatly affect the chemical evolution of the interstellar medium by leading to the formation of complex organic molecules and…

astro-ph.GA2022★ 21 cited

Formation of the simplest amide in molecular clouds: formamide (NHCHO) and its derivatives in HO-rich and CO-rich interstellar ice analogs upon VUV irradiation

K. -J. Chuang, C. J\{"a}ger, S. A. Krasnokutski +2

The astronomical detection of formamide (NHCHO) toward various star-forming regions and in cometary material implies that the simplest amide might have an early origin in dark…

astro-ph.GA2022★ 42 cited

First experimental confirmation of the CH3O + H2CO -> CH3OH + HCO reaction: expanding the CH3OH formation mechanism in interstellar ices

Julia C. Santos, Ko-Ju Chuang, Thanja Lamberts +3

The successive addition of H atoms to CO in the solid phase has been hitherto regarded as the primary route to form methanol in dark molecular clouds. However, recent Monte Carlo s…

physics.bio-ph2022★ 54 cited

A pathway to peptides in space through the condensation of atomic carbon

S. A. Krasnokutski, K. -J. Chuang, C. Jäger +2

Organic molecules are widely present in the dense interstellar medium, and many have been synthesized in the laboratory on Earth under the conditions typical for an interstellar en…

astro-ph.GA2021★ 15 cited

Methoxymethanol Formation Starting from CO-Hydrogenation

Jiao He, Mart Simons, Gleb Fedoseev +7

Methoxymethanol (CH3OCH2OH, MM) has been identified through gas-phase signatures in both high- and low-mass star-forming regions. This molecule is expected to form upon hydrogen ad…

astro-ph.GA2021★ 45 cited

Hydrogenation of accreting C-atoms and CO molecules -- simulating ketene and acetaldehyde formation under dark and translucent cloud conditions

Gleb Fedoseev, Danna Qasim, Ko-Ju Chuang +4

Simple and complex organic molecules (COMs) are observed along different phases of star and planet formation and have been successfully identified in prestellar environments such a…

astro-ph.GA2021★ 25 cited

Methane formation in cold regions from carbon atoms and molecular hydrogen

Thanja Lamberts, Gleb Fedoseev, Marc van Hemert +4

Methane is typically thought to be formed in the solid state on the surface of cold interstellar icy grain mantles via the successive atomic hydrogenation of a carbon atom. In the…

astro-ph.GA2021★ 37 cited

Formation of complex organic molecules in molecular clouds: acetaldehyde, vinyl alcohol, ketene, and ethanol via the "energetic" processing of CH ice

K. -J. Chuang, G. Fedoseev, C. Scirè +5

The simultaneous detection of organic molecules of the form CHO, such as ketene (CHCO), acetaldehyde (CHCHO), and ethanol (CHCHOH), toward early st…

astro-ph.IM2020★ 127 cited

A non-energetic mechanism for glycine formation in the interstellar medium

S. Ioppolo, G. Fedoseev, K. -J. Chuang +8

The detection of the amino acid glycine and its amine precursor methylamine on the comet 67P/Churyumov-Gerasimenko by the Rosetta mission provides strong evidence for a cosmic orig…

astro-ph.SR2020★ 25 cited

A cryogenic ice setup to simulate carbon atom reactions in interstellar ices

D. Qasim, M. J. A. Witlox, G. Fedoseev +7

The design, implementation, and performance of a customized carbon atom beam source for the purpose of investigating solid-state reaction routes in interstellar ices in molecular c…

astro-ph.SR2020★ 84 cited

An experimental study of the surface formation of methane in interstellar molecular clouds

D. Qasim, G. Fedoseev, K. -J. Chuang +4

Methane is one of the simplest stable molecules that is both abundant and widely distributed across space. It is thought to have partial origin from interstellar molecular clouds,…