4 papers · 1 filter
On the double criticality of fluids adsorbed in disordered porous media
E. V. Vakarin, W. Dong, J. P. Badiali
The phase transition of a fluid adsorbed in a heterogeneous system is studied with two simple lattice gas models within the framework of a mean-field theory. Despite the different…
Role of structural fluctuations in the insertion into complex host matrices
E. V. Vakarin, J. P. Badiali
A coupling of structural and thermodynamic fluctuations in the course of various-type insertion processes is investigated within a combination of Gibbsian statistics and the inform…
A correlation between the equilibrium and transport properties of intercalation systems
E. V. Vakarin, J. P. Badiali
Employing the lattice gas model, combined with the linear elasticity theory, a correlation between the equilibrium and transport properties of intercalated species is investigated.…
Thermodynamic non-additivity in disordered systems
E. V. Vakarin, J. P. Badiali
It is shown that there is a mapping of the replica approach to disordered systems with finite replica index on the Tsallis non-extensive statistics, if the average thermodynami…