3 papers
physics.chem-ph2008
Amido Rhenium Trioxides: Cases of Hindered Agostic C-H-M Interactions?
P. Benndorf, M. T. Gamer, P. W. Roesky +2
The amido rhenium trioxides of composition (iPr2N)ReO3, (iPrCyN)ReO3 and (Cy2N)ReO3 (Cy = cyclohexyl) were synthesized in a one pot reaction starting from Re2O7, Me3SiCl and the co…
physics.chem-ph2005
Valence Shell Charge Concentrations at Pentacoordinate d0 Transition Metal Centers: Non-VSEPR Structures of Me2NbCl3 and Me3NbCl2
G. Sean McGrady, Arne Haaland, Hans Peter Verne +5
The molecular structures of the monomeric, pentacoordinated ethylchloroniobium(V) compounds Me3NbCl2 and Me2NbCl3 have been determined by gas electron diffraction (GED)and Density…
cond-mat.mtrl-sci2005
Possible Localization Behavior of the Inherent Conducting Polymer (CH)ReO
E. --W. Scheidt, R. Miller, Ch. Helbig +5
Polymeric methyltrioxorhenium (poly-MTO) represents the first example of an inherent conducting organometallic oxide. It adopts the structural motives and transport properties of s…