4 papers · 1 filter
A Size-Dependent Ideal Solution Model for Liquid-Solid Phase Equilibria Prediction in Aqueous Organic Solutions
Spencer P. Alliston, Chris Dames, Matthew J. Powell-Palm
Predictive synthesis of aqueous organic solutions with desired liquid-solid phase equilibria could drive progress in industrial chemistry, cryopreservation, and beyond, but is limi…
On the equilibrium limit of liquid stability in pressurized aqueous systems
Arian Zarriz, Baptiste Journaux, Matthew J. Powell-Palm
Phase stability, and the limits thereof, are a central concern of materials thermodynamics. However, the temperature limits of equilibrium liquid stability in chemical systems have…
The geometry of high-dimensional phase diagrams: III. Engineering relative stability in four dimensions
Jiadong Chen, Matthew J. Powell-Palm, Wenhao Sun
Designing thermodynamic conditions to improve (or reduce) the stability of a target material is a key task in materials engineering. For example, during materials synthesis one aim…
The geometry of high-dimensional phase diagrams: II. The duality between closed and open chemical systems
Jiadong Chen, Matthew J. Powell-Palm, Wenhao Sun
Modern materials are often synthesized or operated in complex chemical environments, where there can be numerous elemental species, competing phases, and reaction pathways. When an…