activity
20022026
most citedTheory of Structural Glasses and Supercooled Liquids

795 citations · 1.5k across the 23 of their papers we have counts for

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16 papers · 1 filter

cond-mat.dis-nn2018

Low-temperature anomalies in disordered solids: A cold case of contested relics?

Vassiliy Lubchenko

Amorphous solids manifest puzzling effects of mysterious degrees of freedom that give rise to a heat capacity and phonon scattering in great excess over what would be expected for…

cond-mat.dis-nn2017

Aging, jamming, and the limits of stability of amorphous solids

Vassiliy Lubchenko, Peter G. Wolynes

Apart from not having crystallized, supercooled liquids can be considered as being properly equilibrated and thus can be described by a few thermodynamic control variables. In cont…

cond-mat.dis-nn2015★ 68 cited

Theory of the Structural Glass Transition: A Pedagogical Review

Vassiliy Lubchenko

The random first-order transition (RFOT) theory of the structural glass transition is reviewed in a pedagogical fashion. The rigidity that emerges in crystals and glassy liquids is…

cond-mat.dis-nn2014★ 11 cited

Self-consistent elastic continuum theory of degenerate, equilibrium aperiodic solids

Dmytro Bevzenko, Vassiliy Lubchenko

We show that the vibrational response of a glassy liquid at finite frequencies can be described by continuum mechanics despite the vast degeneracy of the vibrational ground state;…

cond-mat.dis-nn2014

On the Mechanism of Activated Transport in Glassy Liquids

Vassiliy Lubchenko, Pyotr Rabochiy

We explore several potential issues that have been raised over the years regarding the "entropic droplet" scenario of activated transport in liquids, due to Wolynes and coworkers,…

cond-mat.dis-nn2013

Microscopically based calculations of the free energy barrier and dynamic length scale in supercooled liquids: The comparative role of configurational entropy and elasticity

Pyotr Rabochiy, Peter G. Wolynes, Vassiliy Lubchenko

We compute the temperature-dependent barrier for alpha-relaxations in several liquids, without adjustable parameters, using experimentally determined elastic, structural, and calor…

cond-mat.dis-nn2010★ 22 cited

Electronic structure and the glass transition in pnictide and chalcogenide semiconductor alloys. Part II: The intrinsic electronic midgap states

Andriy Zhugayevych, Vassiliy Lubchenko

We propose a structural model that treats in a unified fashion both the atomic motions and electronic excitations in quenched melts of pnictide and chalcogenide semiconductors. In…

cond-mat.dis-nn2010★ 23 cited

Electronic structure and the glass transition in pnictide and chalcogenide semiconductor alloys. Part I: The formation of the -network

Andriy Zhugayevych, Vassiliy Lubchenko

Semiconductor glasses exhibit many unique optical and electronic anomalies. We have put forth a semi-phenomenological scenario (J. Chem. Phys. 132, 044508 (2010)) in which several…

cond-mat.dis-nn2010★ 26 cited

Stress distribution and the fragility of supercooled melts

Dmytro Bevzenko, Vassiliy Lubchenko

We formulate a minimal ansatz for local stress distribution in a solid that includes the possibility of strongly anharmonic short-length motions. We discover a broken-symmetry meta…

cond-mat.dis-nn2007★ 16 cited

Charge and momentum transfer in supercooled melts: Why should their relaxation times differ?

Vassiliy Lubchenko

The steady state values of the viscosity and the intrinsic ionic-conductivity of quenched melts are computed, in terms of independently measurable quantities. The frequency depende…

cond-mat.dis-nn2006★ 795 cited

Theory of Structural Glasses and Supercooled Liquids

Vassiliy Lubchenko, P. G. Wolynes

We review the Random First Order Transition Theory of the glass transition, emphasizing the experimental tests of the theory. Many distinct phenomena are quantitatively predicted o…

cond-mat.dis-nn2005★ 13 cited

Electrodynamics of Amorphous Media at Low Temperatures

Vassiliy Lubchenko, Robert J. Silbey, Peter G. Wolynes

Amorphous solids exhibit intrinsic, local structural transitions, that give rise to the well known quantum-mechanical two-level systems at low temperatures. We explain the microsco…

cond-mat.dis-nn2005

The Microscopic Quantum Theory of Low Temperature Amorphous Solids

Vassiliy Lubchenko, Peter G. Wolynes

The quantum excitations in glasses have long presented a set of puzzles for condensed matter physicists. A common view is that they are largely disordered analogs of elementary exc…

cond-mat.dis-nn2004★ 1 cited

Comment on the ``Novel Isotope Effects Observed in Polarization Echo Experiments in Glasses''

Vassiliy Lubchenko, Peter G. Wolynes

The novel isotope and magnetic effects on two level system echoes in glasses observed by Nagel et al.(Phys.Rev.Lett. 92, 245511 (2004)) provide unique experimental insight into the…

cond-mat.dis-nn2003★ 129 cited

Barrier Softening near the onset of Non-Activated Transport in Supercooled Liquids: Implications for Establishing Detailed Connection between Thermodynamic and Kinetic Anomalies in Supercooled Liquids

Vassiliy Lubchenko, Peter G. Wolynes

According to the Random First Order Transition (RFOT) theory of glasses, the barriers for activated dynamics in supercooled liquids vanish as the temperature of a viscous liquid ap…

cond-mat.dis-nn2002★ 168 cited

The Origin of the Boson Peak and the Thermal Conductivity Plateau in Low Temperature Glasses

Vassiliy Lubchenko, Peter G. Wolynes

We argue that the intrinsic glassy degrees of freedom in amorphous solids giving rise to the thermal conductivity plateau and the ``boson peak'' in the heat capacity at moderately…