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physics.chem-ph2026

A Quantum Mechanical Approach to the Computation of Rovibrational Spectra of Diatomic Molecules in Strong Magnetic Fields

Nikhil Yenugu, Ashwani K Tiwari, Sangita Sen

The paper introduces a fully quantum‑mechanical computational method for calculating rovibrational spectra of diatomic molecules, such as H₂, in strong uniform magnetic fields, ext…

physics.chem-ph2026

UGA-SSMRPT2 -- A Multireference Perturbation Theory Predicting Accurate Electronic Excitation Energies in Diverse Molecular Systems

Shamik Chanda, Pratyush Bhattacharjya, Avijit Sen +1

UGA-SSMRPT2, the spin-free perturbative analogue of Mukerjee's State-Specific Multireference Coupled Cluster Theory (MkMRCC) is known to be successful for size-extensive and intrud…

physics.chem-ph2024

Benchmark Computations of Nearly Degenerate Singlet and Triplet states of N-heterocyclic Chromophores : II. Density-based Methods

Shamik Chanda, Subhasish Saha, Sangita Sen

In this paper we demonstrate the performance of several density-based methods in predicting the inversion of S and T states of a few N-heterocyclic fused ring molecules (po…

physics.chem-ph2024

Benchmark Computations of Nearly Degenerate Singlet and Triplet states of N-heterocyclic Chromophores : I. Wavefunction-based Methods

Shamik Chanda, Sangita Sen

In this paper we investigate the role of electron correlation in predicting the S-S and T-S excitation energies and hence, the singlet-triplet gap (E) in…