activity
20122025
most citedSubsurface chemistry of mantles of interstellar dust grains in dark molecular cores

29 citations · 217 across the 22 of their papers we have counts for

collaborators

22 papers

astro-ph.IM2025

The Emergence of Prebiotic Chemistry in the ISM

Izaskun Jimenez-Serra, Giuliana Cosentino, Francisco Montenegro-Montes +22

Contrary to popular belief, the interstellar medium (ISM) is not empty; it is filled with atoms, dust particles, and molecules. Some of these molecules may have been the very build…

astro-ph.GA2025

Redistribution of ices between grain populations in protostellar envelopes. Only the coldest grains get ices

Juris Kalvāns

Context. Matter that falls onto a protoplanetary disk (PPD) from a protostellar envelope is heated before it cools again. This induces sublimation and subsequent re-adsorption of i…

astro-ph.GA2024★ 1 cited

Effects of grain temperature distribution on organic protostellar envelope chemistry

Juris Kalvans, Juris Freimanis

Context. Dust grains in circumstellar envelopes are likely to have a spread-out temperature distribution. Aims. To investigate how trends in temperature distribution between small…

astro-ph.GA2024★ 7 cited

A multigrain-multilayer astrochemical model with variable desorption energy for surface species

Juris Kalvāns, Aija Kalniņa, Kristaps Veitners

Context. Interstellar surface chemistry is a complex process that occurs in icy layers accumulated onto grains of different sizes. Efficiency of surface processes often depends on…

astro-ph.GA2022★ 1 cited

Temperature Spectra of Interstellar Dust Grains Heated by Cosmic Rays. III. Mixed Composition Grains

Juris Kalvans, Juris Roberts Kalnin

Icy grains in the interstellar medium and star-formation regions consist of a variety of materials. Such composite grains interact differently with cosmic-ray (CR) particles compar…

astro-ph.GA2022★ 13 cited

Icy molecule desorption in interstellar grain collisions

Juris Kalvāns, Kedron Silsbee

Observations of gaseous complex organic molecules (COMs) in cold starless and prestellar cloud cores require efficient desorption of the COMs and their parent species from icy mant…

astro-ph.GA2021★ 19 cited

The connection between warm carbon chain chemistry and interstellar irradiation of star-forming cores

Juris Kalvans

Some observations of warm carbon chain chemistry (WCCC) cores indicate that they are often located near the edges of molecular clouds. This finding may suggest that WCCC is promote…

astro-ph.GA2020★ 10 cited

Evaporative cooling of icy interstellar grains II. Key parameters

Juris Kalvāns, Juris Roberts Kalnin

Context. Evaporative (sublimation) cooling of icy interstellar grains occurs when the grains have been suddenly heated by a cosmic-ray (CR) particle or other process. It results in…

astro-ph.GA2019★ 7 cited

Evaporative cooling of icy interstellar grains. I. Basic characterization

Juris Kalvans, Juris Roberts Kalnin

Context. While radiative cooling of interstellar grains is a well-known process, little detail is known about the cooling of grains with an icy mantle that contains volatile adsorb…

astro-ph.GA2019★ 18 cited

Chemical significance of different temperature regimes for cosmic-ray-induced heating of whole interstellar grains

Juris Kalvans, Juris Roberts Kalnin

Cosmic-ray-induced whole-grain heating induces evaporation and other processes that affect the chemistry of interstellar clouds. With recent data on grain heating frequencies as an…

astro-ph.GA2018★ 14 cited

Temperature spectra of interstellar dust grains heated by cosmic-rays II: dark cloud cores

Juris Kalvāns

Cosmic-ray (CR) induced heating of whole interstellar grains is an important desorption mechanism for grain surface molecules in interstellar molecular clouds. This study aims to p…

astro-ph.GA2018★ 26 cited

The efficiency of photodissociation for molecules in interstellar ices

Juris Kalvans

Processing by interstellar photons affects the composition of the icy mantles on interstellar grains. The rate of photodissociation in solids differs from that of molecules in the…

astro-ph.GA2018

The Effects of Subsurface Chemistry in the Grain Mantles on the Deuterium Chemistry in Molecular Clouds

Juris Kalvans, Ivar Shmeld

The deuterium enrichment in molecules in dark molecular cloud cores and starforming regions is usually attributed to gas-phase chemistry. Here we examine the effects of surface and…

astro-ph.HE2016★ 24 cited

Temperature spectra of interstellar dust grains heated by cosmic-rays I: translucent clouds

Juris Kalvāns

Heating of whole interstellar dust grains by cosmic-ray (CR) particles affects the gas-grain chemistry in molecular clouds by promoting molecule desorption, diffusion, and chemical…

astro-ph.GA2015

Ice chemistry in starless molecular cores

Juris Kalvans

Starless molecular cores are natural laboratories for interstellar molecular chemistry research. The chemistry of ices in such objects was investigated with a three-phase (gas, sur…

astro-ph.GA2015★ 24 cited

The effect of selective desorption mechanisms during interstellar ice formation

Juris Kalvans

Major components of ices on interstellar grains in molecular clouds - water and carbon oxides - occur at various optical depths. This implies that selective desorption mechanisms a…

astro-ph.GA2014★ 12 cited

Cosmic-ray-induced dissociation and reactions in warm interstellar ices

Juris Kalvans

Context. Cosmic ray particles that hit interstellar grains in dark molecular cores may induce whole-grain heating. The high temperature of a CR-heated grain allows energy barriers…

astro-ph.GA2014★ 3 cited

Cosmic-ray induced diffusion in interstellar ices

Juris Kalvans

Cosmic rays are able to heat interstellar dust grains. This may enhance molecule mobility in icy mantles that have accumulated on the grains in dark cloud cores. A three-phase astr…

astro-ph.IM2013

Modeling of subsurface ice mantle on interstellar dust grains with astrochemical code ALCHEMIC (research note)

Juris Kalvans

Interstellar ices are layers of molecules deposited on !ne dust grains in dark and dense molecular cloud cores. Subsurface ice has been considered in a few astrochemical models, wh…

astro-ph.GA2013★ 9 cited

Modeling the processing of interstellar ices by energetic particles

Juris Kalvāns, Ivar Shmeld

Context. Interstellar ice is the main form of metal species in dark molecular clouds. Experiments and observations have shown that the ice is significantly processed after the free…

astro-ph.GA2013

The Effect of an Inert Solid Reservoir on Molecular Abundances in Dense Interstellar Clouds

Juris Kalvans, Ivar Shmeld

The question, what is the role of freeze-out of chemical species in determining the molecular abundances in the interstellar gas is a matter of debate. We investigate a theoretical…

astro-ph.GA2012★ 29 cited

Subsurface chemistry of mantles of interstellar dust grains in dark molecular cores

Juris Kalvans, Ivar Shmeld

Context. The abundances of many observed compounds in interstellar molecular clouds still lack an explanation, despite extensive research that includes both gas and solid (dust-gra…