6 papers
Integrating Julia-ITensors into the Tensor Network Quantum Virtual Machine (TNQVM)
Zachary W. Windom, Daniel Claudino, Vicente Leyton-Ortega
The Tensor Network Quantum Virtual Machine (TNQVM) is a high-performance classical circuit simulation backend for the eXtreme-scale ACCelerator (XACC) framework that leverages the…
Analysis of fourth-, fifth-, and infinite-order triple excitations in unitary coupled cluster theory
Zachary W. Windom, Daniel Claudino
In this work, we introduce a correction to the unitary coupled cluster method with single and double excitations (UCCSD) that incorporates the effects of missing triple excitations…
Toward the "platinum standard" of quantum chemistry on quantum computers: perturbative quadruple corrections in unitary coupled cluster theory
Zachary W. Windom, Luke Bertels, Daniel Claudino +1
We propose a non-iterative, post hoc correction to the unitary coupled cluster theory with single, double, and triple excitations (UCCSDT) ansatz, which considers the leading-order…
An "ultimate" coupled cluster method based entirely on
Zachary W. Windom, Ajith Perera, Rodney J. Bartlett
Electronic structure methods built around double-electron excitations have a rich history in quantum chemistry. However, it seems to be the case that such methods are only suitable…
Factorized Quadruples and a Predictor of Higher-Level Correlation in Thermochemistry
James H. Thorpe, Zachary W. Windom, Rodney J. Bartlett +1
Coupled cluster theory has had a momentous impact on the ab initio prediction of molecular properties, and remains a staple ingratiate in high-accuracy thermochemical model chemist…
An attractive way to correct for missing singles excitations in unitary coupled cluster doubles theory
Zachary W. Windom, Daniel Claudino, Rodney J. Bartlett
Coupled cluster methods based exclusively on double excitations are comparatively "cheap" and interesting model chemistries, as they are typically able to capture the bulk of the d…