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cond-mat.soft2024
Quantitatively Connecting Experimental Time-Temperature-Superposition-Breakdown of Polymers near the Glass Transition to Dynamic Heterogeneity via the Heterogeneous Rouse Model
Peijing Yue, David S. Simmons
Polymers near the glass transition temperature Tg often exhibit a breakdown of time-temperature-superposition (TTS), with chain relaxation times and viscosity exhibiting a weaker t…
cond-mat.soft2024
Mixed equilibrium/nonequilibrium effects govern surface mobility in polymer glasses
Jianquan Xu, Asieh Ghanekarade, Li Li +6
The temperature at which supercooled liquids turn into solid-like glasses () can change at the free surface, affecting the properties of nanostructured glasses and their appli…