5 papers
Thermodynamic effects of solid electrolyte interphase formation from solvation and ionic association in water-in-salt electrolytes
Daniel M. Markiewitz, Michael McEldrew, Conor M. E. Phelan +6
Water-in-Salt-Electrolytes (WiSEs) are a promising class of next-generation electrolytes. Unlike classical dilute electrolytes or more conventional battery electrolytes, WiSEs are…
Thermodynamically Consistent Continuum Theory of Magnetic Particles in High-Gradient Fields
Marko Tesanovic, Daniel M. Markiewitz, Marcus L. Popp +2
Magnetic particles underpin a broad range of technologies, from water purification and mineral processing to bioseparations and targeted drug delivery. The dynamics of magnetic par…
Theory of Cation Solvation in the Helmholtz Layer of Li-ion Battery Electrolytes
Zachary A. H. Goodwin, Daniel M. Markiewitz, Qisheng Wu +2
The solvation environments of Li in conventional non-aqueous battery electrolytes, such as LiPF in mixtures of ethylene carbaronate (EC) and ethyl methyl carbonate (EMC), a…
Ionic Associations and Hydration in the Electrical Double Layer of Water-in-Salt Electrolytes
Daniel M. Markiewitz, Zachary A. H. Goodwin, Qianlu Zheng +3
Water-in-Salt-Electrolytes (WiSEs) are an exciting class of concentrated electrolytes finding applications in energy storage devices because of their expanded electrochemical stabi…
On the strength of underscreening
Andreas Härtel, Roland Kjellander
This paper constitutes a presentation of work in progress at a discussion session of the conference Dense ionic fluids Faraday Discussion, 8-10 July 2024, London, and is published…