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cond-mat.soft2011
Ion-sensitive phase transitions driven by Debye-Hückel non-ideality
Kyle J. Welch, Fred Gittes
We find that the Debye-Hückel nonideality of dilute aqueous electrolytes is sufficient to drive volume phase transitions and criticality, even in the absence of a self-attracting o…
cond-mat.soft2011
Ionic phase transitions in non-ideal systems
Kyle J. Welch, Fred Gittes
We construct an explicitly solvable Landau mean-field theory for volume phase transitions of confined or fixed ions driven by relative concentrations of divalent and monovalent cou…