2 papers
physics.chem-ph2026
Spin-cavity interactions in relativistic Jahn-Teller systems under strong light-matter coupling
Eric W. Fischer, Michael Roemelt
We extend our recent work on the cavity-modified spin Zeeman effect of an effective spin-1/2-system[J. Chem. Phys. 163, 174307 (2025)] to a relativistic Jahn-Teller scenario under…
physics.chem-ph2026
Nucleophilic substitution at silicon under vibrational strong coupling: Refined insights from a high-level ab initio perspective
Niels-Ole Frerick, Michael Roemelt, Eric W. Fischer
We study the bimolecular nucleophilic substitution (S2) reaction of 1-phenyl-2-trimethylsilylacetylene (PTA) under vibrational strong coupling (VSC) from the perspecti…