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cond-mat.soft2024

Quantifying the Critical Micelle Concentration of Nonionic and Ionic Surfactants by Self-Consistent Field Theory

Chao Duan, Mu Wang, Ahmad Ghobadi +2

Quantifying the critical micelle concentration (CMC) and understanding its relationship with both the intrinsic molecular structures and environmental conditions are crucial for th…

cond-mat.soft2024

Microphase Segregation in Polyelectrolyte Brushes

Takashi Yokokura, Chao Duan, Rui Wang

Polyelectrolyte (PE) brushes have ubiquitous applications as surface modifiers which regulate various structural and dynamic properties. Here, we apply a continuous-space self-cons…

cond-mat.soft2024

Electrostatic Correlation Augmented Self-Consistent Field Theory and Its Application to Polyelectrolyte Brushes

Chao Duan, Nikhil R. Agrawal, Rui Wang

Modeling ion correlations in inhomogeneous polymers and soft matters with spatially varying ionic strength or dielectric permittivity remains a great challenge. Here, we develop a…

cond-mat.soft2024

Ion Correlation-Driven Hysteretic Adhesion and Repulsion between Opposing Polyelectrolyte Brushes

Chao Duan, Rui Wang

Polyelectrolyte (PE) brushes are widely used in biomaterials and nanotechnology to regulate surface properties and interactions. Here, we apply the electrostatic correlation augmen…

cond-mat.soft2024

A Variational Approach to Trap Macromolecules

Luofu Liu, Chao Duan, Rui Wang

Trapping macromolecules is impoartant for the study of their conformations, interactions, dynamics and kinetic processes. Here, we develop a variational approach which self-consist…