A missing high-spin molecule in the family of cyano-bridged heptanuclear heterometal complexes, [(LCuII)6FeIII(CN)6]3+, and its CoIII and CrIII analogues, accompanied in the crystal by a novel octameric water cluster

Catalin Maxim, Lorenzo Sorace, Panchanana Khuntia +5

Three isostructural cyano-bridged heptanuclear complexes, [{CuII(saldmen)(H2O)}6{MIII(CN)6}](ClO4)3$\cdot$8H2O (M = FeIII 2; CoIII, 3; CrIII 4), have been obtained by reacting the…