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cond-mat.soft2016
Electrostatics of quadrupolarizable media
Radomir I. Slavchov, Iglika M. Dimitrova, Tzanko I. Ivanov
The classical macroscopic Maxwell equations are approximated. They are a corollary of the multipole expansion of the local electrostatic potential up to dipolar terms. But quadrupo…
cond-mat.soft2013
Quadrupole terms in the Maxwell equations: Born energy, partial molar volume and entropy of ions. Debye-Hückel theory in a quadrupolarizable medium
Radomir I. Slavchov, Tzanko I. Ivanov
A new equation of state relating the macroscopic quadrupole moment density to the gradient of the field in an isotropic fluid is derived: $Q = α_Q(\nabla E - U \nabl…