activity
20222024
most citedElectrostatic correlation induced ion condensation and charge inversion in multivalent electrolytes

27 citations · 96 across the 6 of their papers we have counts for

collaborators

6 papers

cond-mat.soft2024

Understanding long-range opposite charge repulsion in multivalent salt solutions

Nikhil R. Agrawal, Carlo Carrao, Rui Wang

The electrostatic correlations between ions profoundly influence the structure and forces within electrical double layers. Here, we apply the modified Gaussian Renormalized Fluctua…

cond-mat.soft2024★ 10 cited

Electrostatic Correlation Augmented Self-Consistent Field Theory and Its Application to Polyelectrolyte Brushes

Chao Duan, Nikhil R. Agrawal, Rui Wang

Modeling ion correlations in inhomogeneous polymers and soft matters with spatially varying ionic strength or dielectric permittivity remains a great challenge. Here, we develop a…

cond-mat.soft2023★ 15 cited

Ion correlation driven like-charge attraction in multivalent salt solutions

Nikhil R. Agrawal, Ravtej Kaur, Carlo Carraro +1

The electrostatic double layer force is key to determining the stability and self-assembly of charged colloids and many other soft matter systems. Fully understanding the attractiv…

cond-mat.soft2022★ 24 cited

On the nature of overcharging and charge inversion in electrical double layers

Nikhil R. Agrawal, Chao Duan, Rui Wang

Understanding overcharging and charge inversion is one of the long-standing challenges in soft matter and biophysics. To study these phenomena, we employ the modified Gaussian reno…

cond-mat.soft2022★ 20 cited

Self-Consistent Description of Vapor-Liquid Interface in Ionic Fluids

Nikhil R. Agrawal, Rui Wang

Inhomogeneity of ion correlation widely exists in many physicochemical, soft matter, and biological systems. Here, we apply the modified Gaussian renormalized fluctuation theory to…

cond-mat.soft2022★ 27 cited

Electrostatic correlation induced ion condensation and charge inversion in multivalent electrolytes

Nikhil R. Agrawal, Rui Wang

The study of the electrical double layer lies at the heart of colloidal and interfacial science. The standard mean-field Poisson-Boltzmann (PB) theory is incapable of modeling many…