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physics.chem-ph2009★ 52 cited
Origin of power laws for reactions at metal surfaces mediated by hot electrons
Thomas Olsen, Jakob Schiøtz
A wide range of experiments have established that certain chemical reactions at metal surfaces can be driven by multiple hot electron mediated excitations of adsorbates. A high tra…
physics.chem-ph2008★ 70 cited
Hot electron mediated desorption rates calculated from excited state potential energy surfaces
Thomas Olsen, Jeppe Gavnholt, Jakob Schiøtz
We present a model for Desorption Induce by (Multiple) Electronic Transitions (DIET/DIMET) based on potential energy surfaces calculated with the Delta Self-Consistent Field extens…