4 papers
Unravelling Chemical Exchanges Through Steady State Free Precession NMR
Sundaresan Jayanthi, Adonis Lupulescu, Mark Shif +2
NMR is uniquely endowed to analyze dynamics, with line shape and relaxation measurements covering timescales over several orders of magnitude. Further insight arises from pulse seq…
Heteronuclear Polarization Transfers Between Spin-locked and Anti-Longitudinal Spin States in the NMR of Liquids and Spinning Solids
Sundaresan Jayanthi, Adonis Lupulescu, Julia Grinshtein +1
Recently, Pang et al reported a novel polarization transfer scheme applicable to three-spin systems, whereby a rotating-frame NMR analogue of the cross effect could transfer polari…
Steady-State Free Precession NMR in the Presence of Heteronuclear Couplings and Decoupling: More Than Meets the Eye
Sundaresan Jayanthi, Zuzana Osifová, Mark Shif +2
Fourier Transform (FT) has been a mainstay of analytical 13C and 15N NMR. On the other hand it has been shown that Steady State Free Precession (SSFP) experiments which depart from…
Phase-Incremented, Steady-State Solution NMR: Maximizing Spectral Sensitivity Without Compromising Resolution
Mark Shif, Yuval Zur, Adonis Lupulescu +3
NMR acquisitions based on Ernst-angle excitations are widely used in analytical spectroscopy, as for over half a century they have been considered the optimal way for maximizing sp…