activity
19962024
most citedTheory of competitive counterion adsorption on flexible polyelectrolytes : Divalent salts

139 citations · 414 across the 12 of their papers we have counts for

collaborators

12 papers

cond-mat.soft2024

Active dynamics of charged macromolecules

Tapas Singha, Siao-Fong Li, Murugappan Muthukumar

We study the role of active coupling on the transport properties of homogeneously charged macromolecules in an infinitely dilute solution. An enzyme becomes actively bound to a seg…

cond-mat.soft2017★ 36 cited

Role of Non-Equilibrium Conformations on Driven Polymer Translocation

Harshwardhan H. Katkar, Murugappan Muthukumar

One of the major theoretical methods in understanding polymer translocation through a nanopore is the Fokker-Planck formalism based on the assumption of quasi-equilibrium of polyme…

physics.flu-dyn2015★ 6 cited

Rotational relaxation time as unifying time scale for polymer and fiber drag reduction

A. M. P. Boelens, M. Muthukumar

Using hybrid Direct Numerical Simulation with Langevin dynamics, a comparison is performed between polymer and fiber stress tensors in turbulent flow. The stress tensors are found…

cond-mat.soft2014★ 55 cited

Enhanced phase segregation induced by dipolar interactions in polymer blends

Rajeev Kumar, Bobby G. Sumpter, M. Muthukumar

We present a generalized theory for studying phase separation in blends of polymers containing dipoles on their backbone. The theory is used to construct co-existence curves and to…

cond-mat.soft2009★ 45 cited

Origin of translocation barriers for polyelectrolyte chains

Rajeev Kumar, M. Muthukumar

For single-file translocations of a charged macromolecule through a narrow pore, the crucial step of arrival of an end at the pore suffers from free energy barriers, arising from c…

cond-mat.soft2008★ 38 cited

Counterion adsorption on flexible polyelectrolytes: comparison of theories

Rajeev Kumar, Arindam Kundagrami, M. Muthukumar

Counterion adsorption on a flexible polyelectrolyte chain in a spherical cavity is considered by taking a "permuted" charge distribution on the chain so that the "adsorbed" counter…