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20212025
most citedDriving chemical reactions with polariton condensates

47 citations · 109 across the 8 of their papers we have counts for

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physics.chem-ph2025

Spin Polarization from Circularly Polarized Light Induced Charge Transfer

Sindhana Pannir-Sivajothi, David T. Limmer

We show how a spin polarization can be generated through the photo-induced electron transfer of an achiral donor-acceptor complex following chiral light excitation. In particular,…

physics.chem-ph2024★ 12 cited

Blackbody radiation and thermal effects on chemical reactions and phase transitions in cavities

Sindhana Pannir-Sivajothi, Joel Yuen-Zhou

An important question in polariton chemistry is whether reacting molecules are in thermal equilibrium with their surroundings. If not, can experimental changes observed in reaction…

physics.chem-ph2024

Precision Franck-Condon spectroscopy from highly-excited vibrational states

Sindhana Pannir-Sivajothi, Joel Yuen-Zhou

As per the Franck-Condon principle, absorption spectroscopy reveals changes in nuclear geometry in molecules or solids upon electronic excitation. It is often assumed these changes…

physics.chem-ph2023

Thermodynamic coupling of reactions via few-molecule vibrational polaritons

Arghadip Koner, Matthew Du, Sindhana Pannir-Sivajothi +2

Interaction between light and molecular vibrations leads to hybrid light-matter states called vibrational polaritons. Even though many intriguing phenomena have been predicted for…

physics.chem-ph2023★ 6 cited

Molecular and solid-state topological polaritons induced by population imbalance

Sindhana Pannir-Sivajothi, Nathaniel P. Stern, Joel Yuen-Zhou

Strong coupling between electronic excitations in materials and photon modes results in the formation of polaritons, which display larger nonlinearities than their photonic counter…

physics.chem-ph2022★ 28 cited

Understanding the Energy Gap Law under Vibrational Strong Coupling

Yong Rui Poh, Sindhana Pannir-Sivajothi, Joel Yuen-Zhou

The rate of non-radiative decay between two molecular electronic states is succinctly described by the energy gap law, which suggests an approximately-exponential dependence of the…

physics.chem-ph2021★ 47 cited

Driving chemical reactions with polariton condensates

Sindhana Pannir-Sivajothi, Jorge A. Campos-Gonzalez-Angulo, Luis A. Martínez-Martínez +2

When molecular transitions strongly couple to photon modes, they form hybrid light-matter modes called polaritons. Collective vibrational strong coupling is a promising avenue for…