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20242026
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physics.chem-ph2026

Full Quantum and Mixed Quantum--Classical Dynamics of Hot Exciton Cooling in Semiconductor Nanocrystals

Bokang Hou, Johan E. Runeson, Samuel L. Rudge +4

Hot-exciton relaxation in semiconductor nanocrystals (NCs) is often described using perturbative theories, but their accuracy is difficult to assess for realistic exciton--phonon H…

physics.chem-ph2026

Selective Biexciton Generation Under Energy-Time Entangled Quantum Light in Quantum Dots

Kaiyue Peng, Chieh Tsao, Hendrik Utzat +1

Energy-time entangled photons provide new opportunities for controlling multiphoton absorption beyond classical limits. Here, we investigate biexciton generation in nanocrystal qua…

physics.chem-ph2026

Photoluminescence Line Shapes of Nanocrystals: Contributions from First- and Second-Order Vibronic Couplings

Kaiyue Peng, Bokang Hou, Kailai Lin +3

We present a microscopic, parameter-free approach for computing the photoluminescence spectra of a single semiconductor nanocrystal. The method derives exciton-phonon coupling dire…

physics.chem-ph2025

Unraveling Exciton Trap Dynamics and Nonradiative Loss Pathways in Quantum Dots via Atomistic Simulations

Bokang Hou, Salvatore Gatto, Samuel L. Rudge +3

Surface defects in colloidal quantum dots are a major source of nonradiative losses, yet the microscopic mechanisms underlying exciton trapping and recombination remain elusive. He…

physics.chem-ph2025

Compact Gaussian basis sets for stochastic DFT calculations

Marcel David Fabian, Eran Rabani, Roi Baer

This work presents new Gaussian single- and double-zeta basis sets optimized for stochastic density functional theory (sDFT) using real-space auxiliary grids. Previous studies show…

physics.chem-ph2025

The Role of Superlattice Phonons in Charge Localization Across Quantum Dot Arrays

Bokang Hou, Matthew Coley-O'Rourke, Uri Banin +2

Understanding charge transport in semiconductor quantum dot (QD) assemblies is important for developing the next generation of solar cells and light-harvesting devices based on QD…