most citedAttosecond soft X-ray pulses generated by chirp-dispersed manipulation in an XFEL reveal nonlinear core-electron dynamics in neon

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physics.chem-ph2026

X-ray Driven Trihydrogen Formation on Silica Nanosurfaces

Samuel Sahel-Schackis, Adam Summers, Ritika Dagar +29

The trihydrogen cation () initiates the ion-molecule reactions that build molecular complexity in interstellar space. Whether its canonical formation reaction, $\ma…

physics.chem-ph2026

Photoinduced enhancement of chemical shift sensitivity to local vibrations

Ana Martínez Gutiérrez, Oliver Alexander, Pablo Estévez Alonso +26

The advent of novel free-electron laser sources enabling time-resolved x-ray photoelectron spectroscopy (tr-XPS) provides a unique opportunity to monitor local chemical environment…

physics.chem-ph2026

Probing the structure of cyclic hydrocarbon molecules with X-ray-induced Coulomb explosion imaging

Kurtis D. Borne, Rebecca Boll, Thomas M. Baumann +27

Coulomb explosion imaging (CEI) is a powerful experimental technique that maps a molecule's geometric structure onto the momenta of ionic molecular fragments produced by rapid mult…

physics.chem-ph2025

Unraveling real-time chemical shifts in the ultrafast regime

Daniel E. Rivas, Lorenzo Paoloni, Rebecca Boll +21

Traditional x-ray photoelectron spectroscopy (XPS) relies upon a direct mapping between the photoelectron binding energies and the local chemical environment, which is well-charact…

physics.chem-ph2025

Unraveling the relaxation dynamics of Uracil: insights from time-resolved X-ray photoelectron spectroscopy

Davide FaccialÃ, Matteo Bonanomi, Bruno Nunes Cabral Tenorio +26

We report a study of the electronic and nuclear relaxation dynamics of the photoexcited RNA base uracil in the gas phase, using time-resolved core level photoelectron spectroscopy…

physics.chem-ph2024

X-ray Coulomb explosion imaging reveals role of molecular structure in internal conversion

Till Jahnke, Sebastian Mai, Surjendu Bhattacharyya +26

Molecular photoabsorption results in an electronic excitation/ionization which couples to the rearrangement of the nuclei. The resulting intertwined change of nuclear and electroni…