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Non-mean-field theory of anomalously large double-layer capacitance
M. S. Loth, Brian Skinner, B. I. Shklovskii
Mean-field theories claim that the capacitance of the double-layer formed at a metal/ionic conductor interface cannot be larger than that of the Helmholtz capacitor, whose width is…
Capacitance of the Double Layer Formed at the Metal/Ionic-Conductor Interface: How Large Can It Be?
Brian Skinner, M. S. Loth, B. I. Shklovskii
The capacitance of the double layer formed at a metal/ionic-conductor interface can be remarkably large, so that the apparent width of the double layer is as small as 0.3 Å. Mean-f…
Ionic conductivity on a wetting surface
Brian Skinner, M. S. Loth, B. I. Shklovskii
Recent experiments measuring the electrical conductivity of DNA molecules highlight the need for a theoretical model of ion transport along a charged surface. Here we present a sim…
Non-monotonic swelling of a macroion due to correlation-induced charge inversion
Brian Skinner, B. I. Shklovskii
It is known that a large, charged body immersed in a solution of multivalent counterions may undergo charge inversion as the counterions adsorb to its surface. We use the theory of…