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most citedChromatographic Peak Shape from Stochastic Model: Analytic Time-Domain Expression in Terms of Physical Parameters and Conditions under which Heterogeneity Reduces Tailing

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physics.chem-ph2026

Chromatographic Peak Shape from a Stochastic-Diffusive Model with Multiple Retention Mechanisms: Analytic Time-Domain Expression and Derivatives

Hernán R. Sánchez

A time-domain analytic expression for chromatographic peak shapes is derived within a stochastic-diffusive framework that incorporates axial diffusion (molecular and multipath/Eddy…