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20242026
most citedCompressible and immiscible fluids with arbitrary density ratio

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cond-mat.stat-mech2026

Density evolution at fluid-fluid interfaces: A generalized Gibbs-Duhem theory

Fei Wang

The classical Gibbs-Duhem relation applies to quasi-static processes and neglects kinetic effects, leaving a fundamental gap between Gibbs thermodynamics and Newtonian mechanics. H…