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cond-mat.stat-mech2025
Thermodynamic Variational Principle Unifying Gravity and Heat Flow
Naoko Nakagawa, Shin-ichi Sasa
Predicting the stable phase configuration in a liquid-gas system becomes a fundamental challenge when the stratification favored by gravity conflicts with arrangements induced by h…
cond-mat.stat-mech2025
Gibbs Factorials Become Kinetic in History-Dependent Reactions
Nanako Hirano, Akira Yoshida, Takenobu Nakamura +1
Gibbs factorials are usually regarded as equilibrium counting factors. We show that they can also appear directly in a measurable kinetic observable when products formed at differe…