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cond-mat.str-el2025
Evaluating covalency using RIXS spectral weights: Silver fluorides vs. cuprates
Ilya Degtev, Daniel Jezierski, Adrián Gómez Pueyo +9
We investigate the electronic structure of AgF2, AgFBF4, AgF and Ag2O using X-ray absorption spectroscopy (XAS) and resonant inelastic X-ray scattering (RIXS) at the Ag L3 edge. XA…
cond-mat.mtrl-sci2025
Magnetic interactions as a pivotal determinant in stabilizing a novel AgIIAgIIIF5 polymorph with high spin AgIII
Daniel Jezierski, Wojciech Grochala
Based on theoretical calculations, we introduce a new AgIIAgIIIF5 monoclinic polymorph with a rare high spin AgIII. Our analysis of the experimental xray diffraction data available…