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Anion Ordering and Phase Stability Govern Optical Band Gaps in BaZr(S,Se)3
Erik Fransson, Michael Xu, Prakriti Kayastha +6
Chalcogenide perovskites have emerged as promising lead free materials for photovoltaic and thermoelectric applications. Among them, BaZrS3 has attracted particular attention due t…
Electronic mobility, doping, and defects in epitaxial chalcogenide perovskite thin films
Jack Van Sambeek, Jessica Dong, Anton V. Ievlev +3
We present the electronic transport properties of (BZS) thin films grown epitaxially by gas-source molecular beam epitaxy (MBE). We observe n-type behavior in al…
Atomic Structure of Self-Buffered BaZr(S,Se) Epitaxial Thin Film Interfaces
Michael Xu, Kevin Ye, Ida Sadeghi +2
Understanding and controlling the growth of chalcogenide perovskite thin films through interface design is important for tailoring film properties. Here, the film and interface str…
A Processing Route to Chalcogenide Perovskites Alloys with Tunable Band Gap via Anion Exchange
Kevin Ye, Ida Sadeghi, Michael Xu +6
We demonstrate synthesis of BaZr(S,Se)3 chalcogenide perovskite alloys by selenization of BaZrS3 thin films. The anion-exchange process produces films with tunable composition and…