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quant-ph2025

Quantum simulation of carbon capture in periodic metal-organic frameworks

Dario Rocca, Jerome F. Gonthier, Joshua Levin +4

Carbon capture is vital for decarbonizing heavy industries such as steel and chemicals. Metal-organic frameworks (MOFs), with their high surface area and structural tunability, are…

quant-ph2025

Improving the runtime of quantum phase estimation for chemistry through basis set optimization

Pauline J. Ollitrault, Jerome F. Gonthier, Dario Rocca +5

Quantum phase estimation (QPE) is a promising quantum algorithm for obtaining molecular ground-state energies with chemical accuracy. However, its computational cost, dominated by…

quant-ph2024

Assessing the query complexity limits of quantum phase estimation using symmetry aware spectral bounds

Cristian L. Cortes, Dario Rocca, Jerome Gonthier +7

The computational cost of quantum algorithms for physics and chemistry is closely linked to the spectrum of the Hamiltonian, a property that manifests in the necessary rescaling of…

quant-ph2024

Enhancing initial state overlap through orbital optimization for faster molecular electronic ground-state energy estimation

Pauline J. Ollitrault, Cristian L. Cortes, Jerome F. Gonthier +7

The quantum phase estimation algorithm stands as the primary method for determining the ground state energy of a molecular electronic Hamiltonian on a quantum computer. In this con…

quant-ph2024

Reducing the runtime of fault-tolerant quantum simulations in chemistry through symmetry-compressed double factorization

Dario Rocca, Cristian L. Cortes, Jerome Gonthier +7

Quantum phase estimation based on qubitization is the state-of-the-art fault-tolerant quantum algorithm for computing ground-state energies in chemical applications. In this contex…