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physics.atom-ph2023
Accurate theoretical determination of the ionization potentials of CaF, SrF, and BaF
A. A. Kyuberis, L. F. Pasteka, E. Eliav +6
We present a comprehensive theoretical study of the ionization potentials of the MF (M= Ca, Sr, Ba) molecules using the state-of-the-art relativistic coupled cluster approach with…
physics.atom-ph2023
Pinning down electron correlations in RaF via spectroscopy of excited states and high-accuracy relativistic quantum chemistry
M. Athanasakis-Kaklamanakis, S. G. Wilkins, L. V. Skripnikov +53
We report the spectroscopy of the 14 lowest excited electronic states in the radioactive molecule radium monofluoride (RaF). The observed excitation energies are compared with full…