most citedFreeze-and-release direct optimization method for variational calculations of excited electronic states

6 citations · 6 across the 4 of their papers we have counts for

collaborators

7 papers

physics.chem-ph2026

Excited-state Properties Beyond the Excitation Energy from Orbital-Optimized Density Functional Calculations II: Absorption Spectra

Lorenzo Restaino, Diego Llorena Prieto, Jukka John +3

Absorption spectra up to 10 eV are calculated for a set of small molecules using a variational density functional approach in which the orbitals are optimized for each excited stat…

physics.chem-ph2026

Excited-state Properties Beyond the Excitation Energy from Orbital-Optimized Density Functional Calculations I: Dipole Moments of Rydberg States

Lorenzo Restaino, Jukka John, Diego Llorena Prieto +3

Rydberg excited states are challenging to describe due to their highly diffuse character. Orbital-optimized density functional calculations typically provide more accurate values o…

physics.chem-ph2026

Orbital Optimization and Neural-Network-Assisted Configuration Interaction Calculations of Rydberg States

Gianluca Levi, Max Kroesbergen, Louis Thirion +5

Rydberg excited states of molecules pose a challenge for electronic structure calculations because of their highly diffuse electron distribution. Even large and elaborate atomic ba…

physics.chem-ph20266 cited

Freeze-and-release direct optimization method for variational calculations of excited electronic states

Yorick L. A. Schmerwitz, Elli Selenius, Gianluca Levi

Variational optimization of orbitals in time-independent density functional calculations of excited electronic states presents a significant challenge, as excited states typically…

physics.chem-ph2025

Natural-Orbital-Based Neural Network Configuration Interaction

Louis Thirion, Yorick L. A. Schmerwitz, Max Kroesbergen +5

Selective configuration interaction methods approximate correlated molecular ground- and excited states by considering only the most relevant Slater determinants in the expansion.…

physics.chem-ph2025

Fine Tuning of the Rotational Rate of Light-Driven, Second Generation Molecular Motors by Fluorine Substitutions

Ivan Tambovtsev, Yorick L. A. Schmerwitz, Gianluca Levi +4

The relaxation time of several second generation molecular motors is analysed by calculating the minimum energy path between the metastable and stable states and evaluating the tra…