most citedHow reproducible are first-principles simulations of liquid water?

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physics.chem-ph2026

Controlling the phase behaviour of ultraconfined water via bilayer graphene stacking

Yixuan Pu, Benjamin X. Shi, Pavan Ravindra +3

Water confined within nanoscale capillaries exhibits phase behaviour and transport properties that differ substantially from bulk, and these effects are commonly interpreted as con…

physics.chem-ph20261 cited

How reproducible are first-principles simulations of liquid water?

Niamh ONeill, Benjamin X. Shi, William J. Baldwin +5

Liquid water is fundamentally important, and its accurate computer simulation has been the driving force for myriad methodological developments. Ab initio molecular dynamics with f…

physics.chem-ph2026

From Accurate Quantum Chemistry to Converged Thermodynamics for Ion Pairing in Solution

Niamh O'Neill, Benjamin X. Shi, William C. Witt +6

Quantitative prediction of thermodynamic properties in solution is essential for translating atomistic simulations into reliable chemical insight. As an exemplar system, the behavi…

physics.chem-ph20261 cited

False Metallization in Short-Ranged Machine Learned Interatomic Potentials

Isaac J. Parker, Mandy J. Hoffmann, William J. Baldwin +7

Machine learned interatomic potentials (MLIPs) have enabled atomistic simulations with ab initio accuracy for a fraction of the computational cost. However, many widely used MLIPs…

physics.chem-ph2025

When Is Nanoconfined Water Different From Interfacial Water?

Xavier R. Advincula, Christoph Schran, Angelos Michaelides

Water behaves very differently at surfaces and under extreme confinement, but the boundary between these two regimes has remained unclear. Despite evidence that interfacial effects…

physics.chem-ph2025

How Accurate Are DFT Forces? Unexpectedly Large Uncertainties in Molecular Datasets

Domantas Kuryla, Fabian Berger, Gábor Csányi +1

Training of general-purpose machine learning interatomic potentials (MLIPs) relies on large datasets with properties usually computed with density functional theory (DFT). A pre-re…