73 citations · 513 across the 21 of their papers we have counts for
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Nonstatistical dynamics on potentials exhibiting reaction path bifurcations and valley-ridge inflection points
Peter Collins, Barry K. Carpenter, Gregory S. Ezra +1
We study reaction dynamics on a model potential energy surface exhibiting post-transition state bifurcation in the vicinity of a valley ridge inflection point. We compute fractiona…
Multiple Transition States and Roaming in Ion-Molecule Reactions: a Phase Space Perspective
Frederic A. L. Mauguiere, Peter Collins, Gregory S. Ezra +2
We provide a dynamical interpretation of the recently identified `roaming' mechanism for molecular dissociation reactions in terms of geometrical structures in phase space. These a…
Bifurcations of Normally Hyperbolic Invariant Manifolds and Consequences for Reaction Dynamics
F. A. L. Mauguiere, P. Collins, G. S. Ezra +1
In this paper we study the breakdown of normal hyperbolicity and its consequences for reaction dynamics; in particular, the dividing surface, the flux through the dividing surface…