4 papers
On the electrical double layer capacitance of the restricted primitive model: a link between the mesoscopic theory and the associative mean spherical approximation
O. Patsahan
The results for the electrical double layer capacitance and the density of ``free ions'' obtained from the mesoscopic theory are compared with the corresponding results of the asso…
Mutual effect of charge- and number-density correlations in ionic liquids and concentrated electrolytes
O. Patsahan, A. Ciach
Correlation functions in concentrated ionic systems are studied within the mesoscopic theory at the level of the Gaussian approximation. The previously neglected fluctuation contri…
Mesoscopic theory for a double layer capacitance in concentrated ionic systems
A. Ciach, O. Patsahan
Effect of an oscillatory decay of the charge density in concentrated ionic solutions and ionic liquids on the double-layer capacitance is studied in a framework of a mesoscopic the…
Phase behaviour of primitive models of molecular ionic liquids in porous media: effects of cation shape, ion association and disordered confinement
T. Hvozd, T. Patsahan, O. Patsahan +2
The phase behaviour of room-temperature ionic liquids (ILs) confined in disordered porous media is studied using a theoretical approach that combines an extension of scaled particl…