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math.OC2024★ 8 cited
Why fixing alpha in the NRTL model might be a bad idea -- Identifiability analysis of a binary Vapor-Liquid equilibrium
Volodymyr Kozachynskyi, Christian Hoffmann, Erik Esche
New vapor-liquid equilibrium (VLE) data are continuously being measured and new parameter values, e.g., for the nonrandom two-liquid (NRTL) model are estimated and published. The p…
math.OC2024
Sequential optimal experimental design for vapor-liquid equilibrium modeling
Martin Bubel, Jochen Schmid, Volodymyr Kozachynskyi +2
We propose a general methodology of sequential locally optimal design of experiments for explicit or implicit nonlinear models, as they abound in chemical engineering and, in parti…