activity
20182022
most citedVariations of the Hartree-Fock fractional-spin error for one electron

11 citations · 18 across the 2 of their papers we have counts for

collaborators

5 papers

physics.chem-ph20227 cited

Density Functionals based on the mathematical structure of the strong-interaction limit of DFT

Stefan Vuckovic, Augusto Gerolin, Timothy J. Daas +3

While in principle exact, Kohn-Sham density functional theory -- the workhorse of computational chemistry -- must rely on approximations for the exchange-correlation functional. De…

physics.chem-ph202111 cited

Variations of the Hartree-Fock fractional-spin error for one electron

Hugh G. A. Burton, Clotilde Marut, Timothy J. Daas +2

Fractional-spin errors are inherent in all current approximate density functionals, including Hartree-Fock theory, and their origin has been related to strong static correlation ef…

physics.chem-ph2021

Noncovalent interactions from models for the Møller-Plesset adiabatic connection

Timothy J. Daas, Eduardo Fabiano, Fabio Della Sala +2

Given the omnipresence of non-covalent interactions (NCIs), their accurate simulations are of crucial importance across various scientific disciplines. Here we construct accurate m…

physics.chem-ph2020

Large coupling-strength expansion of the Møller-Plesset adiabatic connection: From paradigmatic cases to variational expressions for the leading terms

Timothy J. Daas, Juri Grossi, Stefan Vuckovic +5

We study in detail the first three leading terms of the large coupling-strength limit of the adiabatic connection that has as weak-interaction expansion the Møller-Plesset perturba…

physics.chem-ph2018

Investigation of the exchange-correlation potential of functionals based on the adiabatic connection interpolation

E. Fabiano, S. Śmiga, S. Giarrusso +4

We have studied the correlation potentials produced by various adiabatic connection models (ACM) for several atoms and molecules. The results have been compared to accurate referen…