Derivation and thermodynamically consistent coupling of a Debye-Hückel type energy to a steric electrolyte model and application to the apparent molar volume and phase boundaries

Wolfgang Dreyer, Rüdiger Müller

We derive a Debye-Hückel-like model of the electric ion-ion interaction for non-constant dielectric susceptibility, which does not depend on any kind of charging process due to its…