3 papers
cond-mat.mes-hall2009
Electron Transfer Reaction Through an Adsorbed Layer
A. V. B. Cruz, A. K. Mishra, W. Schmickler
We consider electron transfer from a redox to an electrode through and adsorbed intermediate. The formalism is developed to cover all regimes of coverage factor, from lone adsorbat…
cond-mat.mes-hall2009
Electron Transfer rate between a electrode and a bridged redox
A. V. B. Cruz, A. K. Mishra, W. Schmickler
We derive an explict bias dependent expression for electron transfer reaction rate from a solvated redox to a electrode through a bridged molecule of arbitrary length. The interact…
physics.chem-ph1999
Electronic Structure of a Chemisorbed Layer at Electrochemical Interface: Copper Layer on Gold Electrode
A. K. Mishra
An appropriate model Hamiltonian based formalism is proposed for a random adsorbate layer with arbitrary coverage and the ensuing two-dimensional band formation by metallic adsorba…