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20172026
most citedIs the Trotterized UCCSD Ansatz chemically well-defined?

168 citations · 380 across the 29 of their papers we have counts for

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Showing 2022Show all

10 papers · 1 filter

quant-ph2022★ 49 cited

TETRIS-ADAPT-VQE: An adaptive algorithm that yields shallower, denser circuit ansätze

Panagiotis G. Anastasiou, Yanzhu Chen, Nicholas J. Mayhall +2

Adaptive quantum variational algorithms are particularly promising for simulating strongly correlated systems on near-term quantum hardware, but they are not yet viable due, in lar…

quant-ph2022★ 2 cited

Symmetry breaking slows convergence of the ADAPT Variational Quantum Eigensolver

Luke W. Bertels, Harper R. Grimsley, Sophia E. Economou +2

Because quantum simulation of molecular systems is expected to provide the strongest advantage over classical computing methods for systems exhibiting strong electron correlation,…

physics.chem-ph2022

New Local Explorations of the Unitary Coupled Cluster Energy Landscape

Harper R. Grimsley, Nicholas J. Mayhall

The recent quantum information boom has effected a resurgence of interest in unitary coupled cluster (UCC) theory. Our group's interest in local energy landscapes of unitary ansätz…

physics.chem-ph2022

Coupled electron pair-type approximations for tensor product state wavefunctions

Vibin Abraham, Nicholas J. Mayhall

Size extensivity, defined as the correct scaling of energy with system size, is a desirable property for any many-body method. Traditional CI methods are not size extensive hence t…

quant-ph2022★ 1 cited

Scaling adaptive quantum simulation algorithms via operator pool tiling

John S. Van Dyke, Karunya Shirali, George S. Barron +3

Adaptive variational quantum simulation algorithms use information from the quantum computer to dynamically create optimal trial wavefunctions for a given problem Hamiltonian. A ke…

quant-ph2022★ 1 cited

Quantum self-consistent equation-of-motion method for computing molecular excitation energies, ionization potentials, and electron affinities on a quantum computer

Ayush Asthana, Ashutosh Kumar, Vibin Abraham +8

Near-term quantum computers are expected to facilitate material and chemical research through accurate molecular simulations. Several developments have already shown that accurate…