activity
20192025
most citedOn-the-fly ab initio three thawed Gaussians approximation: A semiclassical approach to Herzberg-Teller spectra

31 citations · 52 across the 4 of their papers we have counts for

collaborators

6 papers

physics.chem-ph2025

Vibronic spectra at nonzero temperatures from Herman-Kluk coherence thermofield dynamics

Fabian Kröninger, Caroline Lasser, Jiří J. L. Vaníček

We combine the semiclassical Herman--Kluk approximation with the coherence thermofield dynamics in order to evaluate vibrationally resolved electronic spectra at nonzero temperatur…

physics.chem-ph2025

Thawed Gaussian Ehrenfest dynamics at conical intersections: When can a single mean-field trajectory capture internal conversion?

Alan Scheidegger, Jiří J. L. Vaníček

The thawed Gaussian Ehrenfest dynamics is a single-trajectory method that partially includes both nuclear quantum and electronically nonadiabatic effects by combining the thawed Ga…

physics.chem-ph2023★ 6 cited

Isotope effects in the electronic spectra of ammonia from ab initio semiclassical dynamics

Ēriks Klētnieks, Yannick Calvino Alonso, Jiří J. L. Vaníček

Despite its simplicity, the single-trajectory thawed Gaussian approximation has proven useful for calculating vibrationally resolved electronic spectra of molecules with weakly anh…

physics.chem-ph2020★ 15 cited

How important are the residual nonadiabatic couplings for an accurate simulation of nonadiabatic quantum dynamics in a quasidiabatic representation?

Seonghoon Choi, Jiří Vaníček

Diabatization of the molecular Hamiltonian is a standard approach to removing the singularities of nonadiabatic couplings at conical intersections of adiabatic potential energy sur…

physics.chem-ph2019

On-the-fly ab initio semiclassical evaluation of electronic coherences in polyatomic molecules reveals a simple mechanism of decoherence

Nikolay V. Golubev, Tomislav Begušić, Jiří Vaníček

Irradiation of a molecular system by an intense laser field can trigger dynamics of both electronic and nuclear subsystems. The lighter electrons usually move on much faster, attos…

physics.chem-ph2019★ 31 cited

On-the-fly ab initio three thawed Gaussians approximation: A semiclassical approach to Herzberg-Teller spectra

Tomislav Begušić, Aurélien Patoz, Miroslav Šulc +1

Evaluation of symmetry-forbidden or weakly-allowed vibronic spectra requires treating the transition dipole moment beyond the Condon approximation. To include vibronic spectral fea…