activity
20182021
most citedRoaming at Constant Kinetic Energy: Chesnavich's Model and the Hamiltonian Isokinetic Thermostat

8 citations · 12 across the 4 of their papers we have counts for

collaborators

8 papers

math.DS2021★ 1 cited

Support vector machines for learning reactive islands

Shibabrat Naik, Vladimír Krajňák, Stephen Wiggins

We develop a machine learning framework that can be applied to data sets derived from the trajectories of Hamilton's equations. The goal is to learn the phase space structures that…

math.DS2020

Roaming in acetaldehyde

Vladimír Krajňák, Stephen Wiggins

We investigate roaming in the photodissociation of acetaldehyde (CHCHO), providing insight into the contrasting roaming dynamics observed for this molecule compared to formalde…

nlin.CD2019★ 3 cited

Phase space structures causing the reaction rate decrease in the collinear hydrogen exchange reaction

Vladimír Krajňák, Holger Waalkens

The collinear hydrogen exchange reaction is a paradigm system for understanding chemical reactions. It is the simplest imaginable atomic system with degrees of freedom modeling…

nlin.CD2019★ 8 cited

Roaming at Constant Kinetic Energy: Chesnavich's Model and the Hamiltonian Isokinetic Thermostat

Vladimír Krajňák, Gregory S. Ezra, Stephen Wiggins

We consider the roaming mechanism for chemical reactions under the nonholonomic constraint of constant kinetic energy. Our study is carried out in the context of the Hamiltonian is…

math.DS2019

Using Lagrangian descriptors to uncover invariant structures in Chesnavich's Isokinetic Model with application to roaming

Vladimir Krajnak, Gregory S. Ezra, Stephen Wiggins

Complementary to existing applications of Lagrangian descriptors as an exploratory method, we use Lagrangian descriptors to find invariant manifolds in a system where some invarian…

math.DS2019

Dynamics of the Morse Oscillator: Analytical Expressions for Trajectories, Action-Angle Variables, and Chaotic Dynamics

Vladimír Krajňák, Stephen Wiggins

We consider the one degree-of-freedom Hamiltonian system defined by the Morse potential energy function (the "Morse oscillator"). We use the geometry of the level sets to construct…