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Synthesis of Ultra-Incompressible Carbon Nitrides Featuring Three-Dimensional Frameworks of CN4 Tetrahedra Recoverable at Ambient Conditions
Dominique Laniel, Florian Trybel, Andrey Aslandukov +22
More than thirty years ago, carbon nitrides featuring 3D frameworks of tetrahedral CN4 units were identified as one of the great aspirations of materials science, expected to have…
High-Pressure Na3(N2)4, Ca3(N2)4, Sr3(N2)4, and Ba(N2)3 Featuring Nitrogen Dimers with Non-Integer Charges and Anion-Driven Metallicity
Dominique Laniel, Bjoern Winkler, Timofey Fedotenko +12
Charged nitrogen dimers are ubiquitous in high-pressure binary metal-nitrogen systems. They are known to possess integer formal charges x varying from one through four. Here, we pr…
High-pressure polymeric nitrogen allotrope with the black phosphorus structure
Dominique Laniel, Bjoern Winkler, Timofey Fedotenko +6
Studies of polynitrogen phases are of great interest for fundamental science and for the design of novel high energy density materials. Laser heating of pure nitrogen at 140 GPa in…
High pressure crystal structure and electronic properties of bismuth silicate Bi2SiO5 from synchrotron experiment and first principle calculations
Adrien Girard, Michal Stekiel, Hiroki Taniguchi +4
The high pressure structural properties of bismuth oxide Bi2SiO5 have been investigated up to 28 GPa using in situ powder synchrotron X-ray diffraction and up to 50 GPa with DFT ca…