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Aromatic Hexazine [N6]4- Anion Revealed in the Complex Structure of the High-Pressure Potassium Nitride K9N56
Dominique Laniel, Florian Trybel, Yuqing Yin +13
Recent high-pressure synthesis of pentazolates and subsequent stabilization of the aromatic [N5]- anion at atmospheric pressure had an immense impact on nitrogen chemistry. Here, w…
Fe0.79Si0.07B0.14 metallic glass gaskets for high-pressure research beyond 1 Mbar
Weiwei Dong, Konstantin Glazyrin, Saiana Khandarkhaeva +5
A gasket is an important constituent of a diamond anvil cell (DAC) assembly, responsible for the sample chamber stability at extreme conditions for x-ray diffraction studies. In th…
High-Pressure Na3(N2)4, Ca3(N2)4, Sr3(N2)4, and Ba(N2)3 Featuring Nitrogen Dimers with Non-Integer Charges and Anion-Driven Metallicity
Dominique Laniel, Bjoern Winkler, Timofey Fedotenko +12
Charged nitrogen dimers are ubiquitous in high-pressure binary metal-nitrogen systems. They are known to possess integer formal charges x varying from one through four. Here, we pr…